Seebach’s Conjunctive Reagent Enables Double Cyclizations
نویسندگان
چکیده
منابع مشابه
Stoichiometric and catalytic reductive aldol cyclizations of alkynediones induced by Stryker's reagent.
Conjugate reduction of alkynones by stoichiometric [(Ph(3)P)CuH](6) or catalytic [(Ph(3)P)CuH](6) and polymethyl-hydrosiloxane proceeds to cyclization by an aldol reaction with tethered ketones to generate [small beta]-hydroxyenones with good diastereoselectivity.
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2010
ISSN: 1523-7060,1523-7052
DOI: 10.1021/ol100845z